https://nova.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:50054 Wed 27 Mar 2024 06:58:19 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:37201 0.5Zn_0.5S@halloysite nanotubes tertiary structure is designed via facile in situ assembly, which settles all the above‐mentioned issues and achieves exceptional and stable photocatalytic H₂ evolution and storage. Significantly, EDTA grafted on halloysites as the hole (h⁺) traps steers the photogenerated h⁺ and electrons (e−) from Cd_0.5Zn_0.5S separately to halloysites and outer surface Pt sites, achieving efficient directional separation between h+ and e− and inhibiting the h⁺‐dominated photocorrosion occurring on Cd_0.5Zn_0.5S. Benefiting from these advantages, the hierarchy shows an unprecedented photocatalytic H₂ evolution rate of 25.67 mmol g⁻¹ h⁻¹ with a recording apparent quantum efficiency of 32.29% at λ = 420 nm, which is seven‐fold that of Cd_0.5Zn_0.5S. Meanwhile, an H₂ adsorption capacity of 0.042% is achieved with the room temperature of 25°C and pressure of 2.65 MPa. This work provides a new perspective into designing hierarchical structure for H₂ evolution, and proposes an integration concept for H₂ evolution and storage.]]> Wed 24 Jan 2024 15:11:12 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:41303 Mon 29 Jan 2024 18:04:18 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:17242 Mon 23 Sep 2019 12:37:58 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:35061 2, respectively, in 0.5 M H₂SO₄ solution with a small Tafel slope of 43 mV/dec. Thus it outperforms many of the state-of-art molybdenum-based hydrogen evolution catalysts reported to date.]]> Mon 17 Jun 2019 12:09:40 AEST ]]>